Both alternatives have been widely studied due to the use of mature techniques, i. The second is the steam methane reformer, which converts feedstock and steam to syngas mainly hydrogen and carbon monoxide at high temperature and moderate pressure. The reactions for the two simultaneous smr mechanisms are shown as equations 1 and 2. Due to its maturity, high efficiency, and relatively low cost, steam reforming is considered a viable option for supporting a future hydrogen economy. The effects of reaction parameters, including reaction temperature and space velocity, on hydrogen production via steam reforming of methane srm were investigated using lab and benchscale. Steam reforming of methane in a synthesis gas from biomass. Methane steam reforming reaction behaviour in a packed bed. Steam methane reforming is a widelyused process to convert methane into a mixture of hydrogen and carbon monoxide syngas. C2pt catalyst process technology by gerard b hawkins managing director 2.
The first units commissioned in the 1930s were run on light hydrocarbon feedstock at atmospheric pressure l, it took until 1962 for a 15atm steam reformer to come onstream in the united kingdom using liquid hydrocarbon feedstock 24. Chemical reactions catalyst shape design catalyst chemistry carbon formation and removal 3. The main purpose of this technology is hydrogen production. In order to obtain acceptable reaction rates a catalyst is required to accelerate the process. Methane steam reforming an overview sciencedirect topics. Intrinsic kinetics intrinsic rate equations were derived for the steam reforming of methane, accompanied by watergas shift on a ni mga1204 catalyst.
Methane steam reforming over an niysz solid oxide fuel. A scheme for the low temperature methane steam reforming to produce h2 for fuel cells by burning both unconverted ch4 and h2 to supply the heat for steam methane reforming has been proposed. Comparison of catalyst geometries for methane steam reforming. Pdf the production of synthesis gas by steam reforming. Life cycle assessment of hydrogen production via natural gas. Low temperature methane steam reforming for hydrogen. The steam methane reformer is widely used in industry. Mechanistic investigation of methane steam reforming over ce. Differences in the nature of active sites for methane dry. Pdf cfd simulation of a methane steam reforming reactor. The desulfurized hydrocarbon feed is mixed with superheated process steam in accordance with the steamcarbon relationship necessary for the reforming process. The hfa is composed of a reforming system including the reformer, gas cleanup system, and peripheral components, a hydrogen compressor, storage tanks, and dispenser.
Cfd simulation of a methane steam reforming reactor. Study on catalytic activity toward methane steam reforming. Bireforming of methane from any source with steam and carbon. Kinetics study and modelling of steam methane reforming process over a nioal 2o 3 catalyst in an adiabatic packed bed reactor s. Mechanistic considerations for methane steam reforming msr were derived onthebasisoflangmuirhinshelwood. On the catalytic aspects of steammethane reforming a. A life cycle assessment lca of hydrogen production via natural gas steam reforming was performed to examine the net emissions of greenhouse gases, as well as other major environmental consequences. Preliminary equipment design for onboard hydrogen production. Cost and performance comparison of stationary hydrogen. Presentation about steam reforming modeling and simulatino.
This process contains two chemical reactions which ultimately convert water and methane usually in the form of natural gas into pure hydrogen and carbon dioxide. Conversion of methane steam reforming reaction was studied in a temperatureprogrammed microflow reactor operated at ambient pressure. The production of synthesis gas by steam reforming of methane,brief descritpion about synthesis gas production. In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted with nickel catalyst to produce hydrogen h. In the overall steam methane reforming smr reaction, methane reacts with steam at high temperatures and moderate pressures in catalystfilled tubes to generate synthesis gas, a mixture of hydrogen, carbon monoxide and some carbon dioxide. Jul 28, 20 steam reforming the basics of reforming 1. The catalyst showed stability and activity at a feed molar ratio sc21, wf 0. Thermodynamic analysis helped in reducing the number of possible mechanisms.
Prepared samples were tested when unreduced and reduced prior to reaction for methane dry reforming and methane steam reforming reactivity. The steam reforming plant consists of four basic sections bressan et al. History of synthesis gas in 1780, felice fontana discovered that combustible gas. These onsite units provide a compact, efficient, and flexible alternative to other hydrogen supply schemes. Hydrogen production via steam reforming with co2 capture. The design of the steam reforming process is in part dictated by these constraints. Methane steam reforming is a chemical process to produce hydrogen and synthesis gas mixture by combination of steam and methane in a reformer at appropriate temperature and pressure in presence of suitable metalbased catalysts 4. Steam methane reforming is the most common and economical way to make hydrogen. The methane steam reforming was studied by 26 in a fixed bed tubular quartz micro reactor with cobalt catalyst. The hydrogen produced contains less than 10 ppmv of carbon oxides, but can achieve only a hydrogen concentration between 92 and 97 vol% depending on the severity of the reforming reaction. Nial2o4 in the reduced and unreduced state as well as nial4o7 in the reduced state are active and stable for methane dry reforming due to the presence of 4fold coordinated oxidized nickel. Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. For the baseline hfa, we compared the costs and efficiencies of two hydrogengeneration technologies steam methane reforming and autothermal reforming and two hydrogen purification. Steam methane reforming is the most widely used process for bulk gas production, accounting for 95% of the hydrogen produced in the united states.
Linde is a leading supplier of steam reformer plants with more than 200 constructed units producing capacities of synthesis gas from 300 to over 200,000 nm. Kinetics, catalysis and mechanism of methane steam reforming. Hydrogen production by steam reforming chemical engineering. Co are also active for the methane steam reforming 25. The equilibrium composition out of the steam reformer is shown in fig. Steam reforming before development of psa with a polybed psa system, the co 2 removal system and methanator become redundant. Step i indicates the overall combined reactions, including methane dry reforming, methane steam reforming, methane partial oxidation, and methane oxidation, whereas step ii is the methane cracking reaction to form solid carbon and h 2. This is achieved in a reformer which reacts steam at high temperature and pressure with methane in the presence of a nickel catalyst. Kinetics study and modelling of steam methane reforming. For decades, downfired steam methane reformer furnaces have utilized flue gas tunnels coffins along the radiant section floor to collect and improve flue gas flow uniformity. Steam reforming free download as powerpoint presentation.
Under these conditions, the catalyst presents the average h2co. The steam methane reforming process can be broken down into five distinct steps. Pdf benchscale steam reforming of methane for hydrogen. Steam reforming or steam methane reforming is a chemical synthesis for producing syngas hydrogen and carbon monoxide from hydrocarbons such as natural gas. Redefining steam methane reformer performance in hydrogen. A catalyst with approximately 50 mg was packed in the quartz tube in the reactor. Mahmud school of chemical and process engineering, the university of leeds, ls2 9jt, uk. The first is feedstock treatment where sulphur and other contaminants are removed. Steam methane reforming smr is a chemical process used in the gas manufacturing industry to produce hydrogen on a large scale. Methane steam reforming, methanation and watergas shift. An experimental and modelling study of the pyrolysis and of the steam reforming of methane in mixtures representative of a gas produced from biomass gasification has been performed. Hydroprime plants offer many advantages over traditional supply modes such as electrolytic plants, conventional steam methane plants and truckdelivered bulk hydrogen. For more than 40 years the catalyzed hydroearbonsteam reforming reaction has been of commercial value. Besides these main reactions, the boudouard reaction and the reverse water gasshift reaction were also.
A large number of detailed reaction mechanisms were considered. In order to produce valuable syngas, industrial processes of dry reforming of methane and steam reforming of methane must be further developed. Intrinsic rate equations were derived for the steam reforming of methane, accompanied by water. Methane steam reforming over an niysz solid oxide fuel cell anode in stack configuration d.